Are you faced with the challenge of meeting the measurement accuracy requirements of the Bureau of Land Management (BLM)? And do you have a plan of how you could ensure compliance while staying focused on production rather than gathering samples?
Gas producers must comply with the BLM 43 CFR 3175 regulations, which establish minimum standards for accurate measurement and proper reporting of all gas removed or sold from Federal and Indian (except the Osage Tribe) leases, units, Unit Participating Areas (PAs), and areas subject to Communitization Agreements (CAs).
The BLM rule provides a system for production accountability by operators, lessees, purchasers, and transporters. This rule establishes overall gas measurement performance standards and includes, among other things, requirements for the hardware and software related to gas metering equipment, reporting, and recordkeeping. The BLM rule also identifies certain specific acts of noncompliance that may result in an immediate assessment and provides a process for the BLM to consider variances from the requirements of this rule.
There’s a way to be compliant with these regulations while reducing measurement errors and the costs of complying with 40 CFR 3175. Simplifying the process can allow you to focus on production rather than gathering samples. The approach is to use the appropriate natural gas chromatograph (GC). For example, Emerson’s Rosemount™ 370XA and 770XA GCs reduce BTU measurement errors often found with spot sampling. The online sampling of field-mounted GCs eliminates the need for personnel to frequently travel to the Facility Measurement Point (FMP) to pull a sample; saving man hours and travel costs. The 370XA is ideal for C6+ applications while the 770XA is ideal for C9+ applications or where hydrocarbon liquids may be present. Both are compact in design, don’t require a shelter, offer low utility gas consumption, and operate on 24 Vdc. This makes them perfect for remote locations.
The 370XA and 770XA provide analysis per requirements of the Gas Processors Association (GPA). They offer fully pre-engineered custody transfer application solutions that provide accurate and repeatable measurement analysis for the heating value of natural gas (§§3175.118).
In addition, the use of an advanced GC software solution such as the Emerson MON2020 further simplifies compliance and reduces maintenance and operation costs. The software gives you complete control of the GC either locally or remotely. You can store 88 days of analysis results, over a year of final calibration results, and over 1,700 chromatograms. The analysis report provides heating value and relative density.
In total, a straightforward evaluation of technologies can save natural gas operators both time and money. Managing compliance using the appropriate gas chromatograph not only meets BLM 43 CFR 3175 regulatory requirements, it saves substantial time and money while allowing the user to employ a familiar, proven, and highly accurate technology for the job.
Do you use GCs to meet BLM requirements? What is your approach?
Balancing the right level of gas chromatograph (GC) performance and cost for individual applications and locations within a plant or installation is key for many operators. Increased pressure to optimize processes is driving an increased demand for accurate and timely composition analysis for use in process control and product quality assurance. To continue to meet these demands, Emerson’s Rosemount 1500XA process gas chromatograph adds new enhancements to provide faster compositional feedback and complete, high-resolution analysis, helping operators optimize product specifications and maximize throughput.
The Rosemount™ 1500XA process gas chromatograph is designed for refining, petrochemical, power, and environmental applications where selected components in gaseous or liquid streams must be precisely monitored on a continuous basis. The recent enhancements to the 1500XA enable parallel chromatography, offering oven capacity for up to eight chromatograph valves and four detectors, two of which can be flame detectors. Depending on the application, the 1500XA can include flame ionization or flame photometric detectors for measurement of compounds in the parts-per-billion ranges, or thermal conductivity detectors (TCD) capable of handling applications with parts-per-million measurement requirements.
The 1500XA, like the entire Emerson GC family, is characterized by ease-of-use, ruggedness, and reliability. Emerson is currently the only online GC supplier to offer a lifetime warranty on chromatograph valves. The valves are rated for more than five million operations before repair, which involves simply replacing the diaphragms and can be done easily on-site.
With its numerous valves and detectors, the 1500XA can take a complex analysis application and break it down into smaller, simpler analysis blocks. These blocks are then run in parallel, reducing analysis time and providing faster, easier maintenance and troubleshooting, as well as straightforward data analysis. A complex analysis that may have previously taken 20 minutes may now only take 10 minutes, allowing quicker response to process changes. The 1500XA’s concurrent analysis can be used to reduce the time between analyses by running them at offset times. This can increase the number of analyses within a set time period.
Emerson’s MON2020 software allows the 1500XA to operate completely unattended while making analyzer configuration, maintenance, and data collection easy, either locally or remotely. With intuitive dropdown menus and fill-in-the-blank tables, even new users can quickly navigate through the software.
Since many users are looking for cost-effective and reliable GC solutions, the 1500XA with parallel chromatography and concurrent analysis capabilities more than fulfills that need. When combined with the 370XA and 700XA gas chromatographs, the 1500XA rounds out the widest single selection of gas chromatographs on the market. This makes the Emerson GC family flexible, and reduces costs for integrators and users alike. Used in a wide range of industries, the Emerson GC line allows users to get precisely the performance they require in each location and application while maintaining the same easy-to-use interfaces, the unique software capabilities, and common maintenance requirements.
By Amanda Gogates, Cascade Global Product Manager, Emerson Automation Solutions
Precise and cost-effective measurement of gas purity significantly impacts the bottom line in a number of industrial applications. I’d like to share a new technology with you that will overcome many of the most common problems manufacturers face in this area, including poor sensitivity, costly consumables, and outmoded equipment requiring high levels of technician resourcing to operate and maintain. You may be aware of the Emerson line of Quantum Cascade Laser (QCL) technology for measurement applications such as Continuous Emission Monitoring or CEMS. Now, this remarkable technology has been extended to some of the most demanding markets in the world and is a quantum leap over previous generation solutions.
First, a little background on the technology. Emerson’s QCL technology offers fast, high-resolution spectroscopic detection to identify a range of compounds. QCLs operate in the mid-infrared spectral region, where molecules typically exhibit strong absorption bands that can be exploited to improve measurement sensitivity. Coupled with Tunable Diode Laser (TDL) spectroscopy, a single instrument is now able to broaden measurement capability and exploit both the near- and mid-infrared regions. The result is that a single analyzer is able to monitor an increased number of compounds compared to preceding technologies. The system uses what is called a laser chirp technique. In this technique, a QCL is pulsed with electrical energy and heats up and as the temperature increases, the wavelength of the emitted light also increases. A laser chirp lasts about one microsecond, and in this time a spectrum of between one and three wavenumbers is scanned, sufficient to detect unique absorption features from one or multiple gases. This data can then be interpreted in terms of absolute concentration, minimizing the need for complex and frequent instrument calibration. QCLs can be chirped at a frequency of up to 100 KHz, enabling many thousands of spectra to be gathered in a few seconds, resulting in a high signal-to-noise ratio, while maintaining a rapid response time.
As a result of this unique design, the new CT5800 enables highly accurate measurement of concentrations of impurities down to sub-ppm levels in a variety of gas streams. This makes it ideal for hydrogen purity, nitrogen purity, and ethylene purity applications. With up to six laser modules housed inside the same enclosure, the CT5800 analyzer can measure up to twelve components simultaneously, greatly reducing the need for multiple analyzers while still meeting the real-world analysis needs of these markets.
The key outcome of this new technology is that the combination of this measurement performance and analyzer capabilities has not been possible before – not with existing lasers or other measurement technologies. Of course, not every application needs this level of performance, but when taking the example of ethylene product quality, time and product contamination is money in this volatile industry. When multiple, highly sensitive measurements can be made in seconds by a QCL, excursions in the product quality can be rapidly detected, facilitating decisions to suitably manage plant operation, and minimize losses. QCL technology provides a speed and quality level never before possible. Likewise, the low levels of detection not only improve product quality for the user, but they also open up wider market options and help meet guidelines.
Over the next months, I’ll be sharing about ways to optimize gas analysis in different critical markets. For now, if you have questions about how QCL technology might work for you, please contact me at Amanda.gogates@Emerson.com.
By Neil Widmer, Business Development Manager, Emerson Process Management
Sulfur plant tail gas incinerators are used to oxidize sulfur compounds that cannot be released directly into the atmosphere. These sulfur compounds include H2S, COS and CS2. Incinerators are operated at temperatures that are sufficient for oxidation of the sulfur compounds to SO2, as well as providing the required mechanism for proper plume dispersion. Sulfur plant incinerator control is typically based on a closed loop control on the fuel gas flow to achieve the required incinerator temperature. Natural draft dampers that are manually opened or closed, traditionally supply combustion air. Modern incinerator design incorporates forced draft combustion air. This allows closed loop temperature control where combustion air is provided based on the required ratio to fuel gas. Closed loop control based on excess oxygen can be used to optimize fuel gas control.
Optimizing Sulfur Incinerator Operation with an In-Situ Oxygen Analyzer
Ideal operation of these incinerators is to provide an excess of oxygen in the flue gas stream that ensures complete oxidation of all sulfur compounds to SO2. Sulfur plant incinerators are typically operated with excess oxygen levels of 6 to 10 percent. The recommended operating range for excess oxygen is 2 to 5 percent. Operating below 2 percent may result in insufficient oxidation of the sulfur compounds to SO2. This may result in a violation of the allowable concentrations of H2S, COS and CS2 allowed in the incinerator effluent. Operating above 5 percent excess oxygen will result in an excessive use of incinerator fuel gas. Figure 1 to the right illustrates the relationship between relative fuel demand, stack temperature and excess oxygen concentration.
The most significant advantage of operating within the recommended range is two-fold: Operating above the minimum recommended 2 percent excess oxygen would ensure proper oxidation of sulfur compounds. Operating below the maximum recommended value of 5 percent excess oxygen will provide a reduction in fuel gas usage. An added bonus of operating with a decrease in excess oxygen is the reduction of CO2 (a greenhouse gas) emissions associated with a decrease in fuel gas consumption.
It’s possible to monitor excess oxygen concentrations within the sulfur plant incinerator by using the zirconium-oxide measurement principle. Zirconium oxide is an in situ measurement that provides a fast and reliable measurement of excess oxygen in the sulfur plant incinerator exhaust gas. To counteract the poisoning affect that SO2 has on standard zirconium-oxide sample cells, new sulfur resistant cells are available.
Summary of economic and environmental benefits:
To learn more about instrumentation that can optimize incinerator operation, click HERE.
How do you optimize oxygen levels in your combustion applications?
By Amanda Gogates, Product Manager for Quantum Cascade Laser Analyzers, Emerson Process Management
You may have seen a few stories already on the innovative QCL laser technology. That technology has now been successfully implemented in Emerson’s Rosemount™ CT5100 continuous gas analyzer. It is the world’s only hybrid analyzer to combine Tunable Diode Laser (TDL) and Quantum Cascade Laser (QCL) measurement technologies for process gas analysis and emissions monitoring. The CT5100 provides the most comprehensive analysis available (down to sub ppm) for detecting a range of components, while simplifying operation and significantly reducing costs. The CT5100 can measure up to 12 critical component gases and potential pollutants in a single system – meeting local, state, national, and international regulatory requirements.
But if you’re thinking that the CT5100 is remarkable but “bleeding edge” technology that your application can’t afford – think again. The Rosemount CT5100 operates reliably with no consumables, no in-field enclosure, and a simplified sampling system that does not require any gas conditioning to remove moisture – truly “next generation” technology which saves you money at every turn. The CT5100 is a unique combination of advanced technology and rugged design, and is highly reliable. Its patented laser chirp technique expands gas analysis in both the near- and mid-infrared range, enhancing process insight, improving overall gas analysis sensitivity and selectivity, removing cross interference, and reducing response time. This laser chirp technique produces sharp, well-defined peaks from high resolution spectroscopy that enables specificity of identified components with minimum interference and without filtration, reference cells, or chemometric manipulations.
The rugged Rosemount CT5100 analyzer features –
Give your Emerson representative a call and discuss the potential of the CT5100 in your process gas analysis, continuous emissions monitoring, and ammonia slip applications. This could be a whole new solution to some costly problems. Click HERE for more information on the CT5100.